Lianyungang Qinglang Environmental Technology Co., Ltd.



Lianyungang Sunny Environmental Technology Co., Ltd.

Contact: Manager Dong

Contact number: 13861438488

Address: Guanyun Industrial Park, Lianyungang City, Jiangsu


Manganese nitrate 50% liquid
Manganese nitrate 50% liquid
Manganese nitrate 50% liquid

Safety data sheet

Manganese nitrate 50% liquid

Lianyungang Sunny Environmental Technology Co., Ltd.

According to GHS Sixth Revised Edition

Part One Chemical and Corporate Identity

GG gt; product identification

Product Chinese name50% manganese nitrate solution

Product English nameManganous nitrate;manganese nitrate

Alias50% manganous nitrate solution-

CAS No.10377-66-9

EC No.209-942-9

Molecular formulaMn (NO3) 2

GG gt; Product recommendation and restricted use

Recommended use of the productProduction of manganese metal surface phosphating solution and catalyst.

Restricted use of the productPlease consult the manufacturer.

GG gt; SDS provider information

Applicant nameLianyungang Sunny Environmental Technology Co., Ltd.

Application unit addressGaoxin 8th Road, Dapu Industrial Zone, Lianyungang Economic and Technological Development Zone

Part Two Hazard Identification

According to the United Nations GHS (Sixth Revised Edition) regulations, the hazard category and label elements of the product are as follows:

GG gt; GHS hazard category

Acute Toxicity-OralCategory 4

Harm to the aquatic environmentLong-term hazard category 3

GG gt; GHS label elements


Signal word


GG gt; Hazard statement

H301Toxic if swallowed

H411Toxic to aquatic life with long lasting effects

GG gt; precautionary statement


P264Wash thoroughly after operation.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

Incident response

P370+P378 In case of fire: Use a fire extinguisher to extinguish the fire.

P301+P312 If swallowed: If you feel unwell, call a detoxification center/doctor

P330 Rinse mouth.

P301+P330+P331 If swallowed: Rinse mouth. Do not induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Take off all contaminated clothing immediately. Wash skin/shower with water.

P363 Wash contaminated clothing before reuse.

P304+P340 If inhaled by mistake: Move the person to a place with fresh air and keep a comfortable position for breathing.

P310 Call the detoxification center/doctor immediately.

P305+P351+P338 If in eyes: Rinse carefully with water for several minutes. If you wear contact lenses and can be easily removed, take out the contact lenses. Continue to rinse.

P314 If you feel unwell, seek medical advice/attention.

Safe storage

P405The storage place must be locked.


P501Dispose of contents/container in accordance with local/regional/national/international regulations.

The third part of the composition / composition information

ComponentContent (mass fraction, %)CAS No.EC No.

Manganese Nitrate49.5~50.510377-66-9

Part IV First Aid Measures

GG gt; Description of first aid measures

General adviceFirst aid measures are usually required, please show this SDS to the doctor who arrives at the scene.

eye contactEye contact: Lift the eyelid and rinse with running water or normal saline. Seek medical attention.

skin contactTake off contaminated clothing immediately. Wash the skin with plenty of soap and water. Seek medical attention if you feel unwell.

IngestionDrink enough warm water, induce vomiting, and seek medical attention.

InhaleQuickly leave the scene to a place with fresh air. Keep the airway open. If breathing is difficult, give oxygen. If breathing stops, give artificial respiration immediately. Seek medical attention.

Protection of first respondersEnsure that medical staff understand the hazard characteristics of the product and take self-protective measures to protect themselves and prevent the spread of pollution.

GG gt; the most important symptoms and effects, acute and delayed

1 Limited evidence suggests that repeated or long-term occupational exposure may have cumulative health effects involving organs or biochemical systems.

GG gt; Description of emergency medical treatment and special treatment

1 Perform targeted treatment according to the symptoms that appear.

2 Note that the symptoms may be delayed.

GG gt; Extinguishing media

Part 5 Fire Fighting Measures

Suitable extinguishing mediaDry powder, carbon dioxide or sand.

Unsuitable extinguishing mediaAvoid using too strong water vapor to extinguish the fire, because it may spread the fire.

GG gt; Special hazards from this substance or mixture

1 Inorganic oxidant. Decomposes at high temperature, releasing highly toxic nitrogen oxide gas.

2 Hazardous combustion products: nitrogen oxides.

3 A container exposed to fire may leak its contents through a pressure relief valve.

GG gt; Advice for firefighters

1 When extinguishing a fire, wear a breathing mask ((conforms to MSHA/NIOSH requirements or equivalent)) and wear full protective clothing.

2 Put out the fire at a safe distance and with adequate protection.

3 Prevent fire water from polluting the surface and groundwater system.

Part VI Emergency Treatment of Leakage

GG gt; Protective measures for workers, protective equipment and emergency procedures

1 Ensure adequate ventilation. Remove all ignition sources.

2 Quickly evacuate personnel to a safe area, away from the leakage area and in the upwind direction.

3 Use personal protective equipment. Avoid breathing vapor, smoke, gas or dust.

GG gt; Environmental protection measures

1 While ensuring safety, take measures to prevent further leakage or overflow.

2 Avoid discharge into the surrounding environment.

GG gt; The containment and removal methods of the spilled chemicals and the disposal materials used

1 In case of a small amount of leakage, dry sand or inert absorbent materials can be used to absorb the leakage, and in case of a large amount of leakage, construct a dike or dig a pit for storage. Cover with foam to reduce vapor hazards. Spray water cools and dilutes steam, protects on-site personnel, and dilutes leakage into incombustibles. Use explosion-proof pump to transfer to tank truck or special collector, recycle or transport to waste disposal site for disposal. .

2 Attachments or collections should be stored in suitable airtight containers and disposed of in accordance with relevant local laws and regulations.

3 Remove all ignition sources, and use spark-proof tools and anti-riot equipment.

Part Seven Operation and Storage

GG gt; Operation precautions

1 Operate in a well-ventilated place.

2 Wear suitable personal protective equipment.

3 Avoid contact with skin and eyes.

4 Keep away from heat, sparks, open flames and hot surfaces.

5 Take measures to prevent the accumulation of static electricity.

GG gt; Storage precautions

1 Keep the container tightly closed.

2 Store in a dry, cool and ventilated place.

3 Keep away from heat, sparks, open flames and hot surfaces.

4 Store away from incompatible materials and food containers.

Part VIII Exposure Control/Personal Protection

GG gt; control parameters

Occupational exposure limit

no data

Biological limit

no data

Monitoring method

1EN 14042 Workplace air is used to assess exposure to chemical or biological agents.

2GBZ/T 160.1~GBZ/T 160.81-2004 Determination of Toxic Substances in Workplace Air (series of standards).

GG gt; Engineering Control

1 Maintain adequate ventilation, especially in enclosed areas.

2 Ensure that there are eyewash and shower facilities near the workplace.

3 Use explosion-proof electrical appliances, ventilation, lighting and other equipment.

4 Set up emergency evacuation channels and necessary risk relief areas.

GG gt; personal protective equipment

Eye protectionWear safety glasses.

Hand protectionWear chemical protective gloves (such as butyl rubber gloves). It is recommended to choose to pass the EU EN 374, the US US F739 or

Wear rubber gloves.

Respiratory protectionWhen you may be exposed to its vapor, you must wear a self-priming filter gas mask

Skin and body protectionWear tape protective clothing

Part 9 Physical and Chemical Properties

Appearance and properties: light pink liquidOdor: No information

Odor threshold: no datapH value: no data

Melting point/freezing point (℃): Not availableBoiling point (℃): 100

Flash point (℃) (closed cup): not applicableEvaporation rate: not applicable

Flammability: No dataUpper explosion limit/lower limit [%(v/v)]: upper limit: no data; lower limit: no data

Steam pressure (MPa): Not applicableVapor density (g/mL): Not applicable

Relative density (g/cm³): 1.52 (25℃)Solubility: miscible with water

Partition coefficient of n-octanol/water: not availableAuto-ignition temperature (℃): no information

Decomposition temperature (℃): no informationKinematic viscosity (mm2/s): no data

Part 10 Stability and Reactivity

ReactivityContact with incompatible materials can cause decomposition or other chemical reactions.

Chemical stabilityIt is stable under correct use and storage conditions.


Aggregation hazard

Incompatible materials

Hazardous decomposition products


Do not gather.

no data

Nitrogen oxides.

Part 11 Toxicological Information

GG gt; Acute toxicity

ComponentCAS No.LD50 (oral)LD50 (transdermal)LC50 (inhalation, 4h)

water7732-18-5no datano datano data

Manganese Nitrate20649-39-7no datano datano data

GG gt; skin corrosion/irritation

Corrosive and irritating

GG gt; serious eye damage/irritation

no data

GG gt; skin sensitization

no data

GG gt; respiratory sensitization

no data

GG gt; Germ cell mutagenicity

no data

GG gt; Carcinogenicity


120649-39-7Manganese NitrateNot listedNot listed

GG gt; Reproductive toxicity

no data

GG gt; Reproductive toxicity additional hazard

no data

GG gt; Specific target organ toxicity-single exposure

no data

GG gt; Specific target organ toxicity-repeated exposure

no data

GG gt; Inhalation hazard

no data

Part XII Ecological Information

GG gt; Acute aquatic toxicity

ComponentCAS No.FishCrustaceansAlgae/aquatic plants

Manganese Nitrate20649-39-7no datano datano data

GG gt; Chronic aquatic toxicity

no data

GG gt; other information

Persistence and degradability


Mobility in soil

Results evaluation of PBT and vPvB

no data

no data

no data

Manganese nitrate does not meet the classification criteria of PBT and vPvB in Annex XIII of EU Regulation No 1997/2006.

Part XIII Disposal

Waste chemicalsRefer to relevant national and local regulations before disposal. It is recommended to use incineration for disposal.

Contaminated packagingAfter the packaging is emptied, there may still be residual hazards. It should be kept away from heat and fire sources, and returned to the supplier for recycling if possible.


Disposal considerationsPlease refer to the "Waste Disposal" section.

Part 14 Transportation Information

Shipping label

Marine pollutants

UN Dangerous Goods Number2724

(UN No.)

UN correct shipping nameManganese Nitrate Aqueous Solution

Main hazard categories for transportation5.1Oxidant-like

Transport minor hazard categoryno

Packing category

Part 15 Regulatory Information

GG gt; International Chemical List


Manganese Nitrate×

【EINECS】Inventory of Existing Chemical Substances in Europe


US TSCA Chemical Substance List

Canadian Domestic Chemical Substance List

List of Existing Chemical Substances in China

New Zealand Existing Temporary Chemical Substance List

Philippine inventory of chemicals and chemical substances

List of Existing Chemical Substances in Korea

Australia Existing Chemical Substance List

List of Existing and New Chemical Substances in Japan


"√" means the substance is listed in the regulations

"×" means no information or not listed in regulations

Part Sixteen Other Information

Compilation date2016/09/29

Revision date2016/09/29

Reason for revision-

GG gt; Disclaimer

The format of this safety data sheet meets the requirements of the sixth revised edition of the United Nations GHS system. The data comes from an international authoritative database. Other information is based on the company's current knowledge. We try our best to ensure the accuracy of all the information in it, but due to the diversity of information sources and the limitations of the company's knowledge, this document is only for users' reference. The user of the safety data sheet should judge the rationality of the relevant information according to the purpose of use. We are not responsible for any damages caused by the operation, storage, use or disposal of this product.